Oxidation of luminol by hydrogen per-oxide produces unstable cyclic per-oxide & this on decomposition produces excited triplet 3-aminophthalate first, followed by intersystem crossing to an excited singlet state (forbidden, no emission of light yet). Then the excited singlet state goes to the singlet ground state (allowed) with emission of blue light (λmax = 425 nm). https://www.youtube.com/watch?v=qi9OEPqA9WA | Chemistry Teaching & Learning Video
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